The synthesis behavior of nanoporous silica aerogel in the macroporous ceramic structure was observed using TEOS as a source material and glycerol as a DCCA(dry control chemical additive). Silica aerogel in the macroporous ceramic structure were synthesized through a sono-gel process. The wet gel in the macroporous ceramic structure were aged in ethanol for 72 h at $50^{circ}C$. The aged wet gel was dried under supercritical drying condition. The addition of glycerol has a role of giving the uniform pore size distribution. The reproducibility of aerogel in the macroporous ceramic was improved in the glycerol(0.05 mol%) added to the silica sol and TEOS : $H_2O$=1 : 12.