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Na 및 K 치환에 따른 BaTiO3의 Positive Temperature Coefficient Resistor 특성
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  • Na 및 K 치환에 따른 BaTiO3의 Positive Temperature Coefficient Resistor 특성
저자명
이미재,임태영,김세기,황종희,김진호,서원선,Lee. Mi-Jai,Lim. Tae-Young,Kim. Sei-Ki,Hwang. Jong-Hee,Kim. Jin-Ho,Seo. Won-Seon
간행물명
한국재료학회지
권/호정보
2010년|20권 12호|pp.654-660 (7 pages)
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한국재료학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The influences of Na and K content on the crystal phase, the microstructure and the electrical property of $BaTiO_3$-based thermistors was found to show typical PTC effects. The crystal phase of powder calcined at $1000^{circ}C$ for 4hrs showed a single phase with $BaTiO_3$, and the crystal structure was transformed from tetragonal to cubic phase according to added amounts of Na and K. In XRD results at $43^{circ}sim47^{circ}$, the $(Ba_{0.858}Na_{0.071}K_{0.071})(Ti_{0.9985}Nb_{0.0015})O_{3-delta}$ showed (002) and (200) peaks but the $(Ba_{0.762}Na_{0.119}K_{0.119})(Ti_{0.9975}Nb_{0.0025})O_{3-delta}$ showed (002), (020) and (200) peaks. In sintered bodies, those calcined at $600^{circ}C$ rather than at $1000^{circ}C$ were dense, and for certain amounts of Na and K showed rapid decreases in grain size. In relative permittivity, the curie temperature due to the transformation of ferroelectric phase rose with added Na and K but decreased in terms of relative permittivity. In the result of the R-T curve, the sintered bodies have curie temperatures of about $140^{circ}C$ and the resistivity of sintered bodies have scores of $Omega{cdot}cm$; the jump order of sintered bodies was shown to be more than $10^4$ in powder calcined at $1000^{circ}C$.