The objective of this paper is to study if the EEG spectral relative power would be a reasonable measure of expertise level. EEG electrodes were placed on the locations of Fp1, Fp2, F3, F4, T3, T4, O1, O2 while 5 subjects were playing 4 kinds of game on PC. EEG spectral relative power was significantly related with expertise level on the locations of Fp1, T3, T4, O1, O2. And the results showed that the $ heta$ and $alpha$ activities were decreased, while $eta$ and $gamma$ activities were increased. The results indicated that the EEG spectral relative power would be applicable as a quantitative measure of expertise level.