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950℃ 불순물을 포함한 헬륨 환경에서 CVD β-SiC의 산화
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  • 950℃ 불순물을 포함한 헬륨 환경에서 CVD β-SiC의 산화
저자명
김대종,김원주,장지은,윤순길,김동진,박지연,Kim. Dae-Jong,Kim. Weon-Ju,Jang. Ji-Eun,Yoon. Soon-Gil,Kim. Dong-Jin,Park. Ji-Yeon
간행물명
한국세라믹학회지
권/호정보
2011년|48권 5호|pp.426-432 (7 pages)
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한국세라믹학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The oxidation behavior of CVD ${eta}$-SiC was investigated for Very High Temperature Gas-Cooled Reactor (VHTR) applications. This study focused on the surface analysis of the oxidized CVD ${eta}$-SiC to observe the effect of impurity gases on active/passive oxidation. Oxidation test was carried out at $950^{circ}C$ in the impurity-controlled helium environment that contained $H_2$, $H_2O$, CO, and $CH_4$ in order to simulate VHTR coolant chemistry. For 250 h of exposure to the helium, weight changes were barely measurable when $H_2O$ in the bulk gas was carefully controlled between 0.02 and 0.1 Pa. Surface morphology also did not change based on AFM observation. However, XPS analysis results indicated that a very small amount of $SiO_2$ was formed by the reaction of SiC with $H_2O$ at the initial stage of oxidation when $H_2O$ partial pressure in the CVD ${eta}$-SiC surface placed on the passive oxidation region. As the oxidation progressed, $H_2O$ consumed and its partial pressure in the surface decreased to the active/passive oxidation transition region. At the steady state, more oxidation did not observable up to 250 h of exposure.