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Morphological similarity of a tri-block copolymer processed at ambient and elevated temperatures
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  • Morphological similarity of a tri-block copolymer processed at ambient and elevated temperatures
  • Morphological similarity of a tri-block copolymer processed at ambient and elevated temperatures
저자명
Inceoglu. Sebnem,Aytun. Taner,Menceloglu. Yusuf Z.,Ozen. Ilhan,Acar. Metin H.
간행물명
Korea-Australia rheology journal
권/호정보
2012년|24권 4호|pp.313-321 (9 pages)
발행정보
한국유변학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We investigated the effect of temperature on the morphology of a tri-block copolymer (BCP) processed in a capillary rheometer. The material used was a polystyrene-b-poly(2-ethylhexyl acrylate)-b-polystyrene (PS-b-PEHA-b-PS) tri-block copolymer, which was synthesized by ATRP with a molecular weight of 38.5 K consisting of 49 molar % PEHA. According to the rheological data obtained with dynamic viscoelastic oscillatory measurements, order-disorder temperature (ODT) of the BCP was measured at around $110^{circ}C$. Considering this observation, the samples were studied under different temperatures and pressures (from $110^{circ}C$ to $28^{circ}C$ and from 48 to 75 bar) in capillary rheometer. All processed materials were characterized by using differential scanning calorimetry (DSC) and atomic force microscopy (AFM). It was found that all samples processed by aid of either temperature or pressure showed similar mixed morphologies (a mixture of the ordered and disordered structures i.e., the reduction of microphase separation due to processing).