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The Complete Oxidation of Ethanol at Low Temperature over a Novel Pd-Ce/γ-Al2O3-TiO2 Catalyst
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  • The Complete Oxidation of Ethanol at Low Temperature over a Novel Pd-Ce/γ-Al2O3-TiO2 Catalyst
  • The Complete Oxidation of Ethanol at Low Temperature over a Novel Pd-Ce/γ-Al2O3-TiO2 Catalyst
저자명
Wang. Yanping,Zhao. Jinshuang,Wang. Xiaoli,Li. Zhe,Liu. Pengfei
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2013년|34권 8호|pp.2461-2465 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Pd-$Ce/{gamma}-Al_2O_3-TiO_2$ catalysts were prepared by combined sol-gel and impregnation methods. Transmission electron microscopy, X-ray diffraction, $H_2$-temperature-programmed reduction, $O_2$-temperature-programmed desorption, and ethanol oxidation experiments were conducted to determine the properties of the catalysts. Addition of an optimal amount of Ce improved the performance of the $Pd/{gamma}-Al_2O_3-TiO_2$ catalyst in promoting the complete oxidation of ethanol. The catalyst with 1% Ce exhibited the highest activity, and catalyzed complete oxidation of ethanol at $175^{circ}C$; its selectivity to $CO_2$ reached 87%. Characterization results show that addition of appropriate amount of Ce could enrich the PdO species, and weaken the Pd-O bonds, thus enhancing oxidation ability of the catalyst. Meanwhile, the introduction of $CeO_2$ could make PdO better dispersed on ${gamma}-Al_2O_3-TiO_2$, which is beneficial for the improvement of the catalytic oxidation activity.