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차체 구조용 에폭시 접착제의 접합부 특성에 미치는 Zirconate 첨가효과
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  • 차체 구조용 에폭시 접착제의 접합부 특성에 미치는 Zirconate 첨가효과
저자명
정은택,이혜림,이소정,임창용,서종덕,김목순,김준기,Jeung. Eun-Taek,Lee. Hye-Rim,Lee. So-Jeong,Lim. Chang-Young,Seo. Jong-Dock,Kim. Mok-Soon,Kim. Jun-Ki
간행물명
大韓溶接·接合學會誌
권/호정보
2013년|31권 5호|pp.71-76 (6 pages)
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대한용접접합학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effect of zirconate having - NH functional group on the T-peel and lap shear strength of $CaCO_3$ containing structural epoxy adhesive for car body assembly was investigated. Curing behavior of epoxy adhesive samples were investigated by differential scanning calorimeter (DSC) techniques. The addition of zirconate up to 7.5 phr did not affect the curing mechanism of epoxy adhesive. While the small amount of zirconate addition less than 1.1 phr increased the cross-linking density, the excess addition of zirconate resulted in the increase of uncross-linked impurity. From the increase of T-peel and lap shear strength and the change of fracture mode from the adhesive failure to the mixed one, it was considered that the small addition of zirconate was effective in improving the adhesion strength of epoxy adhesive to the adherend and inorganic filler surfaces. The formation of uncross-linked impurity with the excess addition of zirconate was considered to decrease the joint strength by decreasing the cohesive strength of the cured epoxy.