In this study, we have carried out measurement for exhaust emissions such as particulate matter (PM), nitrogen oxide and carbon oxide from main engines installed on the training ships, HANBADA and HANNARA, of Korea Maritime University. In particular, we considered the two conditions; at arrivals/departures and at constant speed of about 160 rpm. The result showed that the concentration of PM at the ship arrival was 2.41mg/m3. On the other hand, when the ship is on the navigation condition, the concentration of PM was 1.34 mg/m3. The concentrations of nitrogen oxide and carbon oxide were measured in the range of 1,120~1,600 ppm and 320~1,450 ppm at the arrival and departure at the port. Under constant speed condition, the concentrations of nitrogen oxide and carbon oxide were 913~1,470 ppm and 73~460 ppm, respectively. Generally, the concentrations of exhaust emissions under the arrivals and departures were higher than that of constant speed condition. These results imply that the ship operation skill to prevent a sudden load change of main engine is needed during the arrival or departure. In addition, it means that the difference of exhaust emissions according to navigation conditions has to be considered when the reduction technologies of air pollutants from ships are developed.