The local heat transfer and pressure drop of developed turbulent flows in the smooth convergent/divergent channels with rectangular and square cross-sectional areas along the axial distance have been investigated experimentally. The measurement was conducted within the range of Reynolds numbers from 15,000 to 89,000. The channel hydraulic diameter ratios of 0.67 and 1.49 in the rectangular channel with 2 inclined walls and the ratios 0.75 and 1.33 in the square channel with 4 inclined walls are considered. The comparison showed that among the four channels the square divergent channel has the highest thermal performance at the identical mass flow rate, at the identical pumping power, and at the static pressure drop.