The solid phase extractant (PVC-D2EHPA bead) was prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polyvinyl chloride (PVC). The prepared PVC-D2EHPA beads were characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal experiments of Cu(II) by PVC-D2EHPA beads conducted batchwise. The removal kinetics of Cu(II) was found to follow the pseudo-second-order model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity was 2.6 mg/g at $20^{circ}C$. The optimum pH region was in the range of 3.5 to 6. and the standard free energy (${Delta}G^{circ}$) was between -4.67~-4.98 kJ/mol, indicating the spontaneous nature of Cu(II) removal by PVC-D2EHPA beads.