This paper aims to make an artificial arm control strategy. For this, we propose a new feature extraction method and design artificial neural network for the functional classification of myoelectric signal(MES). We first transform the two channel myoelectric signals (MES) for biceps and triceps into frequency domain using fast Fourier transform (FFT). And features were obtained by comparing the magnitudes of ensemble spectrum data and used as inputs to the three-layer neural network for the learning. By changing the number of units in hidden layer of neural network we observed the improvement of classification performance. To observe the effeciency of the proposed scheme we performed experiments for classification of six arm functions to the three subjects. And we obtained on average 94[%] the ratio of classification.