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Vibrational and Electronic Spectroscopic Characterizations of Amino Acid-Metal Complexes
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  • Vibrational and Electronic Spectroscopic Characterizations of Amino Acid-Metal Complexes
  • Vibrational and Electronic Spectroscopic Characterizations of Amino Acid-Metal Complexes
저자명
Han. Jae-Hong,Chi. Yong-Seok
간행물명
Journal of the Korean Society for Applied Biological Chemistry
권/호정보
2010년|53권 6호|pp.821-825 (5 pages)
발행정보
한국응용생명화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

For vibrational and electronic spectroscopic characterizations of ${alpha}$-amino acid mineral chelates, nine water-soluble ${alpha}$-amino acids of Ala, Asn, Gln, His, Ile, Lys, Pro, Thr, and Val were used to prepare metal complexes with Fe(II), Fe(III), Cu(II), and Zn(II) ions. The a-amino acid-metal complexes were characterized by FT-IR and UV-Vis spectrometers to determine the complex formation. The vibrational energy changes of the ammonium and carboxylate groups by FT-IR spectroscopy were characteristic features in the amino acid-metal complex formation. The electronic transition energy changes determined by UV-Vis spectrometer were also characteristic to the Fe(II), Fe(III), and Cu(II) complexes. The amino acid-Zn(II) complexes did not show these changes, because there was no absorption band due to d-d transitions.